2022年6月
Electronic Structure of Carbon Dioxide in Sylgard-184 Evaluated by Using X-ray Emission Spectroscopy
Chemistry Letters
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- 巻
- 51
- 号
- 6
- 開始ページ
- 650
- 終了ページ
- 653
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.220113
To investigate the interactions between carbon dioxide (CO2) and Sylgard-184, which is mainly composed of polydimethylsiloxane and dimethylvinylated and trimethylated silica, the electronic structure of CO2 sorbed in Sylgard-184 was evaluated by using X-ray emission spectroscopy. The spectrum corresponding to the highest occupied molecular orbital of CO2 in the membrane showed a shoulder on the high energy side compared with that of CO2 gas, indicating that the symmetry of the electronic structure was disturbed owing to the interaction with Sylgard components.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.220113
- ISSN : 0366-7022
- eISSN : 1348-0715
- SCOPUS ID : 85133869097