論文

2022年6月

Electronic Structure of Carbon Dioxide in Sylgard-184 Evaluated by Using X-ray Emission Spectroscopy

Chemistry Letters
  • Ryosuke Matsuno
  • ,
  • Yokajaksusri Nutthon
  • ,
  • Akira Miyano
  • ,
  • Kakeru Ninomiya
  • ,
  • Maiko Nishibori
  • ,
  • Hisao Kiuchi
  • ,
  • Shigenori Fujikawa
  • ,
  • Yoshihisa Harada
  • ,
  • Atsushi Takahara

51
6
開始ページ
650
終了ページ
653
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/cl.220113

To investigate the interactions between carbon dioxide (CO2) and Sylgard-184, which is mainly composed of polydimethylsiloxane and dimethylvinylated and trimethylated silica, the electronic structure of CO2 sorbed in Sylgard-184 was evaluated by using X-ray emission spectroscopy. The spectrum corresponding to the highest occupied molecular orbital of CO2 in the membrane showed a shoulder on the high energy side compared with that of CO2 gas, indicating that the symmetry of the electronic structure was disturbed owing to the interaction with Sylgard components.

リンク情報
DOI
https://doi.org/10.1246/cl.220113
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85133869097&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85133869097&origin=inward
ID情報
  • DOI : 10.1246/cl.220113
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • SCOPUS ID : 85133869097

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