2015年5月
Practical Methylenation Reaction for Aldehydes and Ketones Using New Julia-Type Reagents
ORGANIC LETTERS
- ,
- ,
- 巻
- 17
- 号
- 10
- 開始ページ
- 2554
- 終了ページ
- 2557
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1021/acs.orglett.5b01049
- 出版者・発行元
- AMER CHEMICAL SOC
A new Julia-type methylenation reagent, 1-methyl-2-(methylsulfonyl)benzimidazole (1e), reacts with a variety of aldehydes and ketones in the presence of either NaHMLDS (-55 degrees C to rt) or t-BuOK (rt, 1 h) in DMF to give the corresponding terminal alkenes in high yields. The byproducts are easily removed, and the reaction conditions are mild and practical.
- リンク情報
-
- DOI
- https://doi.org/10.1021/acs.orglett.5b01049
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000354908300067&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84929598183&origin=inward
- ID情報
-
- DOI : 10.1021/acs.orglett.5b01049
- ISSN : 1523-7060
- eISSN : 1523-7052
- Web of Science ID : WOS:000354908300067