2003年4月
Organic-inorganic hybrid zeolites containing organic frameworks
Science
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- 巻
- 300
- 号
- 5618
- 開始ページ
- 470
- 終了ページ
- 472
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1126/science.1081019
- 出版者・発行元
- AMER ASSOC ADVANCEMENT SCIENCE
Organic-inorganic hybrid zeolite materials containing an organic framework have been synthesized by partially superseding a lattice oxygen atom by a methylene group. The use of methylene-bridged organosilane as a silicon source gives zeolite materials containing an organic group as lattice (ZOL), with several zeolitic phases such as the MFI and the LTA structures. Through various characterization methods, the presence of methylene frameworks (Si-CH2-Si) that replace siloxane bonds (Si-O-Si) has been verified, although the Si-C bonds are partly cleaved to give rise to terminal methyl groups. The shape-selective lipophilicity of a ZOL material indicates that it is not a physical mixture of conventional zeolite and amorphous organic-containing material but contains a genuine organic-inorganic hybrid zeolite.
- リンク情報
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- DOI
- https://doi.org/10.1126/science.1081019
- CiNii Articles
- http://ci.nii.ac.jp/naid/80015932704
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/12702872
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000182295900034&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0037453464&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=0037453464&origin=inward
- ID情報
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- DOI : 10.1126/science.1081019
- ISSN : 0036-8075
- CiNii Articles ID : 80015932704
- PubMed ID : 12702872
- SCOPUS ID : 0037453464
- Web of Science ID : WOS:000182295900034