2016年3月
Laser THz Emission Spectroscopy of Gas Adsorption-Desorption Dynamics in Tungsten Disulfide Nanosheets
E-JOURNAL OF SURFACE SCIENCE AND NANOTECHNOLOGY
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- 巻
- 14
- 号
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1380/ejssnt.2015.78
- 出版者・発行元
- SURFACE SCI SOC JAPAN
Physically adsorbed gas molecules have dramatic effects on the inherent properties of 2D nanomaterials due to their atomic/molecular-level thinness In this work, we applied laser THz emission spectroscopy to study the gas adsorption-desorption dynamics of tungsten disulfide (WS2) nanosheets prepared by liquid phase exfoliation technique. We find that in low vacuum conditions, NIR irradiation promotes desorption of 02 molecules from WS2 nanosheets. Upon exposure to atmospheric air, results suggest slight photo-oxidation caused by NIR irradiation. Strong photo-oxidation by UV illumination is also confirmed, and we also observed subsequent 02 desorption from WS2 nanosheets by NIR irradiation when the UV illumination is turned off. These results are discussed using the Langmuir adsorption isotherm, which explains the variation of gas adsorption with the gas pressure.
- リンク情報
- ID情報
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- DOI : 10.1380/ejssnt.2015.78
- ISSN : 1348-0391
- Web of Science ID : WOS:000374651500001