2011年3月
Versatile bridging ability of secondary thioamide group for constructing metal cluster based on pincer complex
JOURNAL OF ORGANOMETALLIC CHEMISTRY
- ,
- ,
- 巻
- 696
- 号
- 6
- 開始ページ
- 1305
- 終了ページ
- 1309
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.jorganchem.2010.11.028
- 出版者・発行元
- ELSEVIER SCIENCE SA
The crystallization of the SCS pincer platinum complex with secondary thioamide groups, [4-methyl-2,6-bis(anilinothiocarbonyl)-kappa S-2,S'-phenyl-kappa C-1]chloroplatinum(II), spontaneously forms a trinuclear cluster complex accompanied by liberating HCl in DMSO/EtOH mixture. The crystal structure of the SNS pincer copper complex with secondary thioamide groups, [2,5-bis(benzylaminothiocarbonyl)-kappa S-2,S'-pyrrolyl-kappa N-1] chlorocopper(II), exhibits a dimer structure bearing the bridging thioamide group. The thioamide group acts as the bridging ligand of the multimetallic complexes in different anionic and neutral manners. (C) 2010 Elsevier B. V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.jorganchem.2010.11.028
- ISSN : 0022-328X
- eISSN : 1872-8561
- Web of Science ID : WOS:000287966300027