1999年5月
Can thin disk-like ice clusters be more stable than compact droplet-like ice clusters?
CHEMICAL PHYSICS LETTERS
- ,
- ,
- ,
- 巻
- 304
- 号
- 5-6
- 開始ページ
- 378
- 終了ページ
- 384
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/S0009-2614(99)00293-6
- 出版者・発行元
- ELSEVIER SCIENCE BV
The relative stability of water clusters of two different morphologies has been examined with the size N ranging from 54 to 864; the first one is a circular fragment of bilayer ice (a disk-like cluster), and the second one is a spherical fragment of normal cubic ice (a droplet-like cluster). We found a crossover at N-c similar or equal to 1000, below which the disk-like cluster becomes more energetically favorable. The crossover arises because the potential energy (per molecule) for the droplet-like cluster decreases linearly with N-1/3 whereas it decreases by N-1/2 for the disk-like cluster. (C) 1999 Elsevier Science B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/S0009-2614(99)00293-6
- ISSN : 0009-2614
- Web of Science ID : WOS:000080144200013