Papers

Aug, 2007

Phase equilibria and interfacial tension of fluids confined in narrow pores

JOURNAL OF CHEMICAL PHYSICS
  • Yoshinobu Hamada
  • ,
  • Kenichiro Koga
  • ,
  • Hideki Tanaka

Volume
127
Number
8
First page
84908
Last page
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1063/1.2759926
Publisher
AMER INST PHYSICS

Correlation between phase behaviors of a Lennard-Jones fluid in and outside a pore is examined over wide thermodynamic conditions by grand canonical Monte Carlo simulations. A pressure tensor component of the confined fluid, a variable controllable in simulation but usually uncontrollable in experiment, is related with the pressure of a bulk homogeneous system in equilibrium with the confined system. Effects of the pore dimensionality, size, and attractive potential on the correlations between thermodynamic properties of the confined and bulk systems are clarified. A fluid-wall interfacial tension defined as an excess grand potential is evaluated as a function of the pore size. It is found that the tension decreases linearly with the inverse of the pore diameter or width. (c) 2007 American Institute of Physics.

Link information
DOI
https://doi.org/10.1063/1.2759926
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000249156300075&DestApp=WOS_CPL
ID information
  • DOI : 10.1063/1.2759926
  • ISSN : 0021-9606
  • eISSN : 1089-7690
  • Web of Science ID : WOS:000249156300075

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