For one-qubit pure quantum states, it is already proved that the Voronoi diagrams with respect to two distances -Euclidean distance and the quantum divergence - coincide. This fact is a support for a known method to calculate the Holevo capacity. To consider an applicability of this method to quantum states of a higher level system, it is essential to check if the coincidence of the Voronoi diagrams also occurs. In this paper, we show a negative result for that expectation. In other words, we mathematically prove that those diagrams no longer coincide in a higher dimension. That indicates that the method used in one-qubit case to calculate the Holevo capacity might not be effective in a higher dimension. © 2006 IEEE.