2010年
Stereocontrolled Synthesis of Spiro[n.2]alkenes by Ring Contraction of Fused-Cyclobutanols
CHEMISTRY-A EUROPEAN JOURNAL
- ,
- ,
- 巻
- 16
- 号
- 28
- 開始ページ
- 8427
- 終了ページ
- 8432
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/chem.201000930
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
An unusual ring-contraction rearrangement to give spirocyclopropanes from fused cyclobutanols (see scheme) has been developed. It is found that the strain energy of the substrates derived from an additional fused ring and the stereoelectronic effect of the migrating a bond are important factors. It is noteworthy that the rearrangement proceeds in a stereospecific manner. Moreover, the method provides a spiro(cyclopropane indane) framework from tricyclo[6.3.0.02,5]undecane, which corresponds to illudane and the protoilludane skeleton.
- リンク情報
-
- DOI
- https://doi.org/10.1002/chem.201000930
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201002210766490260
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/20549753
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000280819100026&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-77954844294&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0002-1798-7919
- ID情報
-
- DOI : 10.1002/chem.201000930
- ISSN : 0947-6539
- eISSN : 1521-3765
- J-Global ID : 201002210766490260
- ORCIDのPut Code : 45409560
- PubMed ID : 20549753
- SCOPUS ID : 77954844294
- Web of Science ID : WOS:000280819100026