A novel order-disorder phase transition in glasses via ultra fast laser irradiation is first time reported. The Raman spectra of modified region is highly dependent on the polarization of probe beam, indicating the bond orientation at the outer structure of modified region is no longer isotropic and a long-range-order is induced which could be analogue with liquid crystals. The ordered glass phase is not expected from inorganic materials and further investigation is needed. (C) 2011 Elsevier B. V. All rights reserved.