2016年
The controlled synthesis of polyglucose in one-dimensional coordination nanochannels
CHEMICAL COMMUNICATIONS
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- 巻
- 52
- 号
- 29
- 開始ページ
- 5156
- 終了ページ
- 5159
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c6cc01357k
- 出版者・発行元
- ROYAL SOC CHEMISTRY
We demonstrate a feasible method for the preparation of polyglucose (PGlc) with controlled structures, where the polymerization of glucose monomers was performed using one-dimensional nanochannels of [La(1,3,5-benzenetrisbenzoate)(H2O)](n) (1). Cationic ring-opening polymerization of 1,6-anhydro-beta-D-glucose (levoglucosan) using 1 gave a quasi-linear PGlc, which contrasts highly with the results obtained from conventional polymerizations in bulk and solution. The regulated structure of PGlc prepared using the PCP led to a remarkable improvement in the processability and thermal stability of PGlc, which is useful in applications as a bioplastic.
- リンク情報
- ID情報
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- DOI : 10.1039/c6cc01357k
- ISSN : 1359-7345
- eISSN : 1364-548X
- Web of Science ID : WOS:000373629800017