論文

国際誌
2021年1月5日

Crystallization-induced mechanofluorescence for visualization of polymer crystallization.

Nature communications
  • Sota Kato
  • ,
  • Shigeki Furukawa
  • ,
  • Daisuke Aoki
  • ,
  • Raita Goseki
  • ,
  • Kazusato Oikawa
  • ,
  • Kousuke Tsuchiya
  • ,
  • Naohiko Shimada
  • ,
  • Atsushi Maruyama
  • ,
  • Keiji Numata
  • ,
  • Hideyuki Otsuka

12
1
開始ページ
126
終了ページ
126
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1038/s41467-020-20366-y

The growth of lamellar crystals has been studied in particular for spherulites in polymeric materials. Even though such spherulitic structures and their growth are of crucial importance for the mechanical and optical properties of the resulting polymeric materials, several issues regarding the residual stress remain unresolved in the wider context of crystal growth. To gain further insight into micro-mechanical forces during the crystallization process of lamellar crystals in polymeric materials, herein, we introduce tetraarylsuccinonitrile (TASN), which generates relatively stable radicals with yellow fluorescence upon homolytic cleavage at the central C-C bond in response to mechanical stress, into crystalline polymers. The obtained crystalline polymers with TASN at the center of the polymer chain allow not only to visualize the stress arising from micro-mechanical forces during polymer crystallization via fluorescence microscopy but also to evaluate the micro-mechanical forces upon growing polymer lamellar crystals by electron paramagnetic resonance, which is able to detect the radicals generated during polymer crystallization.

リンク情報
DOI
https://doi.org/10.1038/s41467-020-20366-y
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/33402691
PubMed Central
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7785725
ID情報
  • DOI : 10.1038/s41467-020-20366-y
  • PubMed ID : 33402691
  • PubMed Central 記事ID : PMC7785725

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