論文

査読有り
2013年3月

Formation of a porphyrin/fullerene light-harvesting system from self-assembly of porphyrin-end-functionalized polycyclohexane and [6,6]-phenyl-C61-butyric acid methyl ester: Effects of microphase separation and p-p interactions

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
  • Itaru Natori
  • ,
  • Shizue Natori
  • ,
  • Anna Kanasashi
  • ,
  • Kosuke Tsuchiya
  • ,
  • Kenji Ogino

51
5
開始ページ
368
終了ページ
375
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/polb.23222
出版者・発行元
WILEY-BLACKWELL

Thin films composed of zinc tetraphenylporphyrin-end-functionalized polycyclohexane (ZnTPP-PCHE) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) blends were prepared to investigate their potential as light-harvesting systems within polymer solar cells (PSCs). Both the microphase separation characteristics and the extent of pp interactions in these ZnTPP-PCHE/PCBM blends had significant effects on the optical properties of the films. The extent to which the absorption bands of the films overlapped the terrestrial solar spectrum was increased considerably when the blends formed a co-continuous structure, even though films of pure ZnTPP-PCHE or PCBM exhibited only weak absorption over that wavelength region. We conclude that these polymer blend films may be considered as viable candidates for light-harvesting systems within PSCs. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2013

リンク情報
DOI
https://doi.org/10.1002/polb.23222
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000313982700007&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/polb.23222
  • ISSN : 0887-6266
  • Web of Science ID : WOS:000313982700007

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