論文

査読有り
2017年3月

Photoinduced Charge Separation Catalyzed by Manganese Oxides onto a Y-Shaped Branching Acceptor Efficiently Preventing Charge Recombination

CHEMPHYSCHEM
  • Kentaro Yamamoto
  • ,
  • Kazuo Takatsuka

18
5
開始ページ
537
終了ページ
548
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/cphc.201601237
出版者・発行元
WILEY-V C H VERLAG GMBH

A full-dimensional nonadiabatic electron wavepacket study is performed on Mn oxide catalytic charge separation to be created on an accepting molecular system, which is of Y-shaped structure and has a track-branching function for protons and electrons. This branching is necessary in cases in which the transferred electrons and protons are to be eventually carried to mutually different destinations without quick annihilation of the created pair (charge separation). However, as a result of the larger size of such a branched acceptor, the distance between the Mn oxide and the acceptor is so great that it is far from obvious whether an electron is successfully delivered through conical intersections. It is shown here that this can actually occur.

リンク情報
DOI
https://doi.org/10.1002/cphc.201601237
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000395423100014&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/cphc.201601237
  • ISSN : 1439-4235
  • eISSN : 1439-7641
  • ORCIDのPut Code : 51275830
  • Web of Science ID : WOS:000395423100014
  • ORCIDで取得されたその他外部ID : a:1:{i:0;a:1:{s:0:"";s:0:"";}}

エクスポート
BibTeX RIS