2018年
Electrochemical formation of selenium nanoparticle in an amide-type ionic liquid
Electrochemistry
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- 巻
- 86
- 号
- 2
- 開始ページ
- 57
- 終了ページ
- 60
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.5796/electrochemistry.17-00076
- 出版者・発行元
- Electrochemical Society of Japan
Electrochemical formation of selenium (Se) nanoparticles in an amide-type ionic liquid, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing selenium tetrachloride (SeCl4) was investigated in the presence of excess chloride anion on a glassy carbon electrode. Electrochemical reduction of [SeCl6]2- resulted in deposition of Se on the electrode surface. The deposited Se was further reduced electrochemically at the more negative potential region to form [Se2]2-, which was suggested to exist by ultraviolet-visible spectroscopy. Se nanoparticles dispersed in the ionic liquid were formed by the proportionation reaction between [SeCl6]2- and [Se2]2- in the ionic liquid. The Se nanoparticles were characterized by energy dispersive X-ray spectroscopy and transmission electron microscopy.
- リンク情報
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- DOI
- https://doi.org/10.5796/electrochemistry.17-00076
- URL
- http://orcid.org/0000-0001-8904-6790
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85042849712&origin=inward 本文へのリンクあり
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85042849712&origin=inward
- ID情報
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- DOI : 10.5796/electrochemistry.17-00076
- ISSN : 2186-2451
- ISSN : 1344-3542
- eISSN : 2186-2451
- ORCIDのPut Code : 46454062
- SCOPUS ID : 85042849712