論文

査読有り
2018年

Electrochemical formation of selenium nanoparticle in an amide-type ionic liquid

Electrochemistry
  • Hiroki Sato
  • ,
  • Shimul Saha
  • ,
  • Naoki Tachikawa
  • ,
  • Kazuki Yoshii
  • ,
  • Nobuyuki Serizawa
  • ,
  • Yasushi Katayama

86
2
開始ページ
57
終了ページ
60
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.5796/electrochemistry.17-00076
出版者・発行元
Electrochemical Society of Japan

Electrochemical formation of selenium (Se) nanoparticles in an amide-type ionic liquid, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing selenium tetrachloride (SeCl4) was investigated in the presence of excess chloride anion on a glassy carbon electrode. Electrochemical reduction of [SeCl6]2- resulted in deposition of Se on the electrode surface. The deposited Se was further reduced electrochemically at the more negative potential region to form [Se2]2-, which was suggested to exist by ultraviolet-visible spectroscopy. Se nanoparticles dispersed in the ionic liquid were formed by the proportionation reaction between [SeCl6]2- and [Se2]2- in the ionic liquid. The Se nanoparticles were characterized by energy dispersive X-ray spectroscopy and transmission electron microscopy.

リンク情報
DOI
https://doi.org/10.5796/electrochemistry.17-00076
URL
http://orcid.org/0000-0001-8904-6790
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85042849712&origin=inward 本文へのリンクあり
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85042849712&origin=inward
ID情報
  • DOI : 10.5796/electrochemistry.17-00076
  • ISSN : 2186-2451
  • ISSN : 1344-3542
  • eISSN : 2186-2451
  • ORCIDのPut Code : 46454062
  • SCOPUS ID : 85042849712

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