論文

査読有り 筆頭著者 責任著者
2020年12月

Thermodynamic assessment of the Ga–Se–Te system

Calphad
  • Yuheng Liu
  • ,
  • Zhichao Dou
  • ,
  • Masanori Enoki
  • ,
  • Yutaka Oyama
  • ,
  • Hiroshi Ohtani

71
開始ページ
102206
終了ページ
102206
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.calphad.2020.102206
出版者・発行元
Elsevier BV

In this study, the Ga-Te binary system was reassessed by means of the CALPHAD method using a modified lattice stability parameter for Te as well as experimental data for this binary system. The two-sublattice ionic solution model was applied for the liquid phase, and the intermediate phases were described by the sublattice model. A set of self-consistent thermodynamic parameters was optimized for all the phases in the Ga-Te binary system, which reproduced the phase diagram and the thermodynamic properties well. Using the reevaluated Ga-Te system, previously assessed Ga-Se system, and modified Se-Te system, a critical evaluation of the Ga-Se-Te ternary system was performed. The calculated vertical sections, isothermal sections, and liquidus projection agreed reasonably well with the experimental data. Immiscibility in the liquid phase was observed, and the origin of this behavior is discussed from a thermodynamic perspective.

リンク情報
DOI
https://doi.org/10.1016/j.calphad.2020.102206
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000589922000003&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.calphad.2020.102206
  • ISSN : 0364-5916
  • eISSN : 1873-2984
  • Web of Science ID : WOS:000589922000003

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