論文

査読有り
2022年1月

Palladium-Catalyzed [1,3]-O-to-N Rearrangement of Allylic ­Imidates

Synlett
  • Yusuke Kuroda

33
01
開始ページ
98
終了ページ
102
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1055/s-0041-1737140
出版者・発行元
Georg Thieme Verlag KG

<title>Abstract</title>The rearrangement of allylic imidates is a powerful transformation for the synthesis of allylic amines. Whereas the [3,3]-rearrangement has long been established as the Overman rearrangement, the corresponding [1,3]-rearrangement is rare. Here, we report a novel strategy for the [1,3]-rearrangement of imidates based on the oxidative addition of a palladium(0) catalyst to an allylic imidate. Structurally distinct allylic amides could be synthesized under mild and base-free conditions.

リンク情報
DOI
https://doi.org/10.1055/s-0041-1737140
URL
http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0041-1737140.pdf
ID情報
  • DOI : 10.1055/s-0041-1737140
  • ISSN : 0936-5214
  • eISSN : 1437-2096

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