2022年1月
Palladium-Catalyzed [1,3]-O-to-N Rearrangement of Allylic Imidates
Synlett
- 巻
- 33
- 号
- 01
- 開始ページ
- 98
- 終了ページ
- 102
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1055/s-0041-1737140
- 出版者・発行元
- Georg Thieme Verlag KG
<title>Abstract</title>The rearrangement of allylic imidates is a powerful transformation for the synthesis of allylic amines. Whereas the [3,3]-rearrangement has long been established as the Overman rearrangement, the corresponding [1,3]-rearrangement is rare. Here, we report a novel strategy for the [1,3]-rearrangement of imidates based on the oxidative addition of a palladium(0) catalyst to an allylic imidate. Structurally distinct allylic amides could be synthesized under mild and base-free conditions.
- リンク情報
- ID情報
-
- DOI : 10.1055/s-0041-1737140
- ISSN : 0936-5214
- eISSN : 1437-2096