2006年7月
Preparation and structure of new phenylplatinum complexes containing silsesquioxane as a monodentate or bidentate ligand
ORGANOMETALLICS
- ,
- ,
- 巻
- 25
- 号
- 15
- 開始ページ
- 3776
- 終了ページ
- 3783
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/om060192s
- 出版者・発行元
- AMER CHEMICAL SOC
Incompletely condensed silsesquioxanes, R7Si7O9(OH)(3) (R = cyclo-C5H9, iso-C4H9), react with trans- PtI(Ph)(L)(2)] (L = PEt3, PMe2Ph) at room temperature in the presence of Ag2O to yield platinum complexes with a monodentate O-coordinated silsesquioxane, trans-[Pt{O10Si7R7(OH)(2)}(Ph)(L)(2)] (1a: R = cyclo-C5H9; L = PEt3, 1b: R = iso-C4H9; L = PEt3, 2a: R = cyclo-C5H9; L = PMe2Ph, 2b: R = iso-C4H9; L= PMe2Ph). Reactions of silsesquioxanes with trans-[ PtI(Ph)(PPh3)(2)] in the presence of Ag2O at 55 degrees C afford unexpected Pt-Ag heterobimetallic complexes, [Pt{O11Si7R7(OH)(AgPPh3)}(Ph)(PPh3)] (3a: R = cyclo-C5H9, 3b: R = iso-C4H9), and a hydroxo-bridged dinuclear platinum complex, anti-[{PtPh- PPh3)}(2)(mu-OH)(2)] (4). These complexes were isolated and characterized by X-ray crystallography and H-1, P-31, Si-29, and C-13 NMR spectroscopy. The crystal structures of 3a and 3b show a square-planar coordination around the Pt center bonded to Ph, PPh3, and bidentate O, O-coordinated silsesquioxane. One of the coordinated oxygen atoms is also bound to the AgPPh3 group.
- リンク情報
- ID情報
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- DOI : 10.1021/om060192s
- ISSN : 0276-7333
- CiNii Articles ID : 30011434071
- Web of Science ID : WOS:000238848600036