2008年1月
An efficient synthesis of fluorocyclopentenes using fluoroalkylidenecarbenes
TETRAHEDRON LETTERS
- ,
- ,
- ,
- ,
- 巻
- 49
- 号
- 1
- 開始ページ
- 76
- 終了ページ
- 79
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1016/j.tetlet.2007.11.019
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
An efficient synthesis of fluorocyclopentenes is described. By treatment of (2-fluoroalkenyl)iodonium salts with potassium tert-butoxide, (alpha-fluoroalkylidene)carbenes were generated efficiently to give fluorocyclopentenes via 1,5-C-H insertion. Fluorocyclopentenes having a functionality, such as chlorine, acetoxy, or ketone, and a spiro fluorocyclopentene were synthesized in good yields. (C) 2007 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.tetlet.2007.11.019
- ISSN : 0040-4039
- CiNii Articles ID : 80018038568
- Web of Science ID : WOS:000252152500016