論文

査読有り
2014年12月1日

Development of a novel cesium adsorbent which causes minimal hydraulic resistance through the immobilization of Prussian blue analogues in a monolithic silica-alumina microhoneycomb

Chemical Engineering Transactions
  • Shin R. Mukai
  • ,
  • Yoshinao Kimura
  • ,
  • Seiichiro Yoshida
  • ,
  • Isao Ogino

42
開始ページ
181
終了ページ
186
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.3303/CET1442031
出版者・発行元
Italian Association of Chemical Engineering - AIDIC

Prussian blue analogues (PBAs) such as K2[CuFe(CN)6] are expected to become the key material for efficient cesium recovery. However to use this material efficiently, it must have a morphology that doesn't cause a severe hydraulic resistance, as a high throughput is required during recovery. This is very difficult, as this material is usually obtained in the form of small particles. In this work, we developed a cesium adsorbent with a low hydraulic resistance using PBAs as the adsorption sites. Silica-alumina was selected as the substrate. As for the morphology of the adsorbent, we adopted a microhoneycomb structure, which can be obtained by the Ice Templating Method, a new micromolding method developed in our laboratory. The obtained adsorbent showed a significantly lower hydraulic resistance than conventional adsorbents in the particle form, and could be used to continuously remove ppm-ordered cesium from solutions.

リンク情報
DOI
https://doi.org/10.3303/CET1442031
ID情報
  • DOI : 10.3303/CET1442031
  • ISSN : 2283-9216
  • SCOPUS ID : 84946575809

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