Papers

Peer-reviewed
2017

Crystal structure of [N,N-bis(diphenylphosphorothioyl)amidato-κ2 S,S′]bis(triphenylphosphane-κP)copper(I) dichloromethane monosolvate

Acta Crystallographica Section E: Crystallographic Communications
  • Tatsuya Nishi
  • ,
  • Toshiaki Tsukuda
  • ,
  • Michihiro Nishikawa
  • ,
  • Taro Tsubomura

Volume
73
Number
8
First page
1105
Last page
1107
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1107/S2056989017009380
Publisher
International Union of Crystallography

The title compound, [Cu(C24H20NP2S2)(C18H15P)2]·CH2Cl2 or [Cu(dppaS2)-(PPh3)2]·CH2Cl2, is a neutral mononuclear copper(I) complex bearing an N,N-bis(diphenylphosphorothioyl)amidate (dppaS2 -) ligand and two triphenylphosphane ligands. The molecular structure shows that the two S atoms of the dppaS2 - ligand [Cu - S = 2.3462 (9) and 2.3484 (9) Å] and the two P atoms of the two triphenylphosphane ligands [Cu - P = 2.3167 (9) and 2.2969 (9) Å] coordinate to the copper(I) atom, resulting in a tetrahedral coordination geometry. The crystallographically observed molecular structure is compared to the results of DFT calculations.

Link information
DOI
https://doi.org/10.1107/S2056989017009380
ID information
  • DOI : 10.1107/S2056989017009380
  • ISSN : 2056-9890
  • SCOPUS ID : 85029472999

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