2017
Crystal structure of [N,N-bis(diphenylphosphorothioyl)amidato-κ2 S,S′]bis(triphenylphosphane-κP)copper(I) dichloromethane monosolvate
Acta Crystallographica Section E: Crystallographic Communications
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- ,
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- Volume
- 73
- Number
- 8
- First page
- 1105
- Last page
- 1107
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1107/S2056989017009380
- Publisher
- International Union of Crystallography
The title compound, [Cu(C24H20NP2S2)(C18H15P)2]·CH2Cl2 or [Cu(dppaS2)-(PPh3)2]·CH2Cl2, is a neutral mononuclear copper(I) complex bearing an N,N-bis(diphenylphosphorothioyl)amidate (dppaS2 -) ligand and two triphenylphosphane ligands. The molecular structure shows that the two S atoms of the dppaS2 - ligand [Cu - S = 2.3462 (9) and 2.3484 (9) Å] and the two P atoms of the two triphenylphosphane ligands [Cu - P = 2.3167 (9) and 2.2969 (9) Å] coordinate to the copper(I) atom, resulting in a tetrahedral coordination geometry. The crystallographically observed molecular structure is compared to the results of DFT calculations.
- Link information
- ID information
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- DOI : 10.1107/S2056989017009380
- ISSN : 2056-9890
- SCOPUS ID : 85029472999