A detailed investigation on the main characteristics was conducted on a novel and unique group of industrially produced mesoporous silica material. Six materials from a TMPS group were selected in the respect to their pore size ranging from 1.8 nm up to 4.2 nm. Four of the selected samples were also made with silica doping making them potentially attractive for water adsorption applications with the advantage of the pore-tuning possibilities for specific use. The surface area, pore volume and pore size distribution of these materials were established by standard nitrogen adsorption at T = 77.4 K showing typical values of mesoporous silica materials such as high surface area in the range from 600 to 750 m2g−1 and pore volumes reaching 0.38 cm3g−1 in the case of the smallest TMPS-1.5A and 0.98 cm3g−1 in the case of the largest TMPS-4R. The wall thickness was found out regular around 1.5 ~ 2 nm with lower values attributed to bigger pore sized samples promising good structural integrity. Specific heat showed regular values through all the samples at ~ 0.85 J g−1K−1. Additional information on the structural characteristics and the effect on the amount of silanol group presence and the difference on regular and aluminium-doped samples were studied by means of 29Si DD/MAS NMR. Additionally, elemental analysis by EDS was conducted as well. All the characteristics of the TMPS materials were compared to the standard mesoporous silica materials SBA-15 and MCM-41.