2016年2月
Electrochemical properties of LiCoPO4-thin film electrodes in LiF-based electrolyte solution with anion receptors
JOURNAL OF POWER SOURCES
- ,
- ,
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- 巻
- 306
- 号
- 開始ページ
- 753
- 終了ページ
- 757
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.jpowsour.2015.12.105
- 出版者・発行元
- ELSEVIER SCIENCE BV
Compatibility of LiF + anion receptors/propylene carbonate (PC) electrolyte solution with high potential positive electrode for lithium-ion batteries was examined by cyclic voltammetry. As anion receptors, tripropyl borate (TPB), tris(pentafluorophenyl) borane (TPFPB), and tris(hexafluoroisopropyl) borate (THFIPB) were used. LiCoPO4 thin-film electrodes were prepared by sol gel method and used as both carbon- and binder-free model electrodes. From cyclic voltammograms, LiCoPO4 showed better cycle ability in 0.1 mol dm(-3) LiF + 0.1 mol dm(-3) THFIPB/PC, however, other anion receptors did not give positive influence. It is indicated that the surface protecting layer from F--THFIPB complex and made LiCoPO4 stable. Electrochemical behavior depending on anion receptors was discussed according to reaction activity of F-. (C) 2015 Elsevier B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.jpowsour.2015.12.105
- ISSN : 0378-7753
- eISSN : 1873-2755
- Web of Science ID : WOS:000370309300093