2016年9月
Efficient Enantioselective Synthesis of Oxahelicenes Using Redox/Acid Cooperative Catalysts
Journal of the American Chemical Society
- ,
- ,
- ,
- ,
- ,
- ,
- 巻
- 138
- 号
- 36
- 開始ページ
- 11481
- 終了ページ
- 11484
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jacs.6b07424
- 出版者・発行元
- American Chemical Society ({ACS})
An efficient and enantioselective synthesis of oxa[9]helicenes has been established via vanadium(V)-catalyzed oxidative coupling/intramolecular cyclization of polycyclic phenols. A newly developed vanadium complex cooperatively functions as both a redox and Lewis acid catalyst to promote the present sequential reaction and afford oxa[9]helicenes in good yields with up to 94% ee.
- リンク情報
- ID情報
-
- DOI : 10.1021/jacs.6b07424
- ISSN : 0002-7863
- ORCIDのPut Code : 37423537
- Web of Science ID : WOS:000383410700015