論文

査読有り
2020年2月

Mechanochromic Luminescence from Crystals Consisting of Intermolecular Hydrogen-Bonded Sheets

CHEMISTRY-AN ASIAN JOURNAL
  • Yoshimitsu Sagara
  • ,
  • Kiyonori Takahashi
  • ,
  • Takayoshi Nakamura
  • ,
  • Nobuyuki Tamaoki

15
4
開始ページ
478
終了ページ
482
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/asia.201901679
出版者・発行元
WILEY-V C H VERLAG GMBH

Introduction of functional groups that can form intermolecular hydrogen bonds into highly-emissive luminophores is a promising way to induce mechanochromic luminescence. Herein, we report that a 9,10-bis(phenylethynyl)anthracene derivative featuring two amide groups forms green-emissive crystals based on two-dimensional hydrogen-bonded molecular sheets. Mechanical grinding changed the emission from green to yellow, owing to a transition from a crystalline to an amorphous phase. Infrared spectroscopy revealed that mechanical stimuli disrupted the linear hydrogen-bonding formation. A thermal treatment recovered the original green photoluminescence.

リンク情報
DOI
https://doi.org/10.1002/asia.201901679
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000508624300001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/asia.201901679
  • ISSN : 1861-4728
  • eISSN : 1861-471X
  • Web of Science ID : WOS:000508624300001

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