Jul, 2013
Donor-Acceptor Segregated Paracyclophanes Composed of Naphthobipyrrole and Stacked Fluoroarenes
ORGANIC LETTERS
- ,
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- Volume
- 15
- Number
- 13
- First page
- 3202
- Last page
- 3205
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1021/ol400882q
- Publisher
- AMER CHEMICAL SOC
The expeditious synthesis of donor-acceptor segregated paracyclophanes has been achieved by a selective SNAr reaction of hexafluorobenzene with o-dipyrrolylbenzenes and subsequent cyclodehydrogenation. An orthogonally arranged D-A segregated structure was confirmed by X-ray crystallography. The combined results of DFT calculations and absorption spectra revealed the charge transfer (CT) nature from the naphthobipyrrole (donor) to the stacked fluoroarene moiety (acceptor).
- Link information
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- DOI
- https://doi.org/10.1021/ol400882q
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000321605800003&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84879996259&origin=inward
- ID information
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- DOI : 10.1021/ol400882q
- ISSN : 1523-7060
- eISSN : 1523-7052
- SCOPUS ID : 84879996259
- Web of Science ID : WOS:000321605800003