Aug, 2011
Star-Shaped Pyrrole-Fused Tetrathiafulvalene Oligomers: Synthesis and Redox, Self-Assembling, and Conductive Properties
ORGANIC LETTERS
- ,
- ,
- ,
- Volume
- 13
- Number
- 15
- First page
- 3896
- Last page
- 3899
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1021/ol2014279
- Publisher
- AMER CHEMICAL SOC
A series of star-shaped pyrrole-fused tetrathiafulvalene (TTF) oligomers 1-3 was synthesized via an S(N)Ar reaction of fluorinated benzenes with the pyrrolyl sodium salts. Electrochemical and chemical oxidations of 1-3 revealed that a radical cation moiety on each TTF unit was successfully accumulated in all oligomers. Self-assembled structures of neutral and oxidized species were characterized by SEM and XRD, and their conductive properties of the Iodine-doped 1-3 as well as an intermolecular mixed-valence ion radical salt were investigated.
- Link information
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- DOI
- https://doi.org/10.1021/ol2014279
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000293252800033&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=79961067088&origin=inward
- ID information
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- DOI : 10.1021/ol2014279
- ISSN : 1523-7060
- eISSN : 1523-7052
- SCOPUS ID : 79961067088
- Web of Science ID : WOS:000293252800033