2019年4月
Fluorous Property of a Short Perfluoroalkyl-Containing Compound Realized by Self-Assembled Monolayer Technique on a Silicon Substrate
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
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- 巻
- 92
- 号
- 4
- 開始ページ
- 785
- 終了ページ
- 789
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/bcsj.20180356
- 出版者・発行元
- CHEMICAL SOC JAPAN
Fluorous properties represented by water-and-oil repellency are perfluoroalkyl (R-f) compound-specific characteristics, which are widely used for surface coating of glass, electronic devices and textiles for preventing water and grease fouling. According to the stratified dipole-arrays (SDA) theory, the minimum R-f length of (CF2)(7) is theoretically necessary for realizing fluorous properties. Unfortunately, however, production of compounds involving this chemical unit is strictly banned because of concerns of environmental pollution, which is a big dilemma. Here, we show that the fluorous properties can be realized by self-assembled monolayer (SAM) even with a short R-f-containing compound, since the SAM technique makes the best use of the self-aggregation property of the R-f groups, and it readily makes the molecules immobile.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.20180356
- ISSN : 0009-2673
- eISSN : 1348-0634
- Web of Science ID : WOS:000462311800006