論文

査読有り
2019年4月

Fluorous Property of a Short Perfluoroalkyl-Containing Compound Realized by Self-Assembled Monolayer Technique on a Silicon Substrate

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
  • Kise, Ryuma
  • ,
  • Fukumi, Aki
  • ,
  • Shioya, Nobutaka
  • ,
  • Shimoaka, Takafumi
  • ,
  • Sonoyama, Masashi
  • ,
  • Amii, Hideki
  • ,
  • Takagi, Toshiyuki
  • ,
  • Kanamori, Toshiyuki
  • ,
  • Eda, Kazuo
  • ,
  • Hasegawa, Takeshi

92
4
開始ページ
785
終了ページ
789
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/bcsj.20180356
出版者・発行元
CHEMICAL SOC JAPAN

Fluorous properties represented by water-and-oil repellency are perfluoroalkyl (R-f) compound-specific characteristics, which are widely used for surface coating of glass, electronic devices and textiles for preventing water and grease fouling. According to the stratified dipole-arrays (SDA) theory, the minimum R-f length of (CF2)(7) is theoretically necessary for realizing fluorous properties. Unfortunately, however, production of compounds involving this chemical unit is strictly banned because of concerns of environmental pollution, which is a big dilemma. Here, we show that the fluorous properties can be realized by self-assembled monolayer (SAM) even with a short R-f-containing compound, since the SAM technique makes the best use of the self-aggregation property of the R-f groups, and it readily makes the molecules immobile.

リンク情報
DOI
https://doi.org/10.1246/bcsj.20180356
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000462311800006&DestApp=WOS_CPL
ID情報
  • DOI : 10.1246/bcsj.20180356
  • ISSN : 0009-2673
  • eISSN : 1348-0634
  • Web of Science ID : WOS:000462311800006

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