論文

査読有り
2000年7月

Nuclear-spin relaxation of Co-59 correlated with the spin-state transitions in LaCoO3

PHYSICAL REVIEW B
  • Y Kobayashi
  • ,
  • N Fujiwara
  • ,
  • S Murata
  • ,
  • K Asai
  • ,
  • H Yasuoka

62
1
開始ページ
410
終了ページ
414
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1103/PhysRevB.62.410
出版者・発行元
AMER PHYSICAL SOC

The Co-59-NMR on single crystals of LaCoO3 has been studied in order to investigate the spin-stale transition through the nuclear-spin relaxation in this compound. Below T similar to 35 K, the spin-lattice and spin-spin relaxation rates show a thermal-activation-type temperature dependence with an energy gap of similar to 180 K. This value is close to the energy difference between the low spin state (S=0) and the intermediate spin state (S=1) predicted in the two-stage spin-state transition model with the intermediate spin state. The apparent spin-spin relaxation rates depend on the resonance peaks split due to the nuclear-electric-quadrupole interaction, which is explained by an indirect nuclear spin-spin interaction through the interacting paramagnetic electron spins. This observation is consistent with the ferromagnetic short-range correlation among the electron spins on Co3+ ions confirmed by neutron-scattering experiments.

リンク情報
DOI
https://doi.org/10.1103/PhysRevB.62.410
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000088037000072&DestApp=WOS_CPL
ID情報
  • DOI : 10.1103/PhysRevB.62.410
  • ISSN : 1098-0121
  • eISSN : 1550-235X
  • Web of Science ID : WOS:000088037000072

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