2020年7月21日
Grafting conductive polymers on graphene oxide through cross-linker: A stepwise approach
Journal of Materials Chemistry A
- ,
- 巻
- 8
- 号
- 27
- 開始ページ
- 13718
- 終了ページ
- 13724
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/d0ta05489e
- 出版者・発行元
- ROYAL SOC CHEMISTRY
A three-step reaction furnished a composite of graphene and a conductive polymer. In the first step, graphene oxide was modified with a diamine, which acted as a linker for polymer attachment. In the second step, an initiating site was attached to the free amine of the linker. Finally, a polymer was grown from the initiation site, and graphene oxide was reduced during polymer growth. The method does not require any catalyst, acid, or reducing agent, furnishing the graphene-polymer composite in a straightforward procedure. Various instrumental techniques, including step-by-step AFM analysis, were used to characterize the structure of the products in each step and confirm the covalent functionalization among graphene oxide, cross-linker, and polymer. The average surface height was sequentially increased after each step, indicating the success of the sequential reactions. The graphene-polymer composite showed excellent electrochemical performance and stability compared with a composite prepared by physical mixing of graphene and polymer.
- リンク情報
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- DOI
- https://doi.org/10.1039/d0ta05489e
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000548452100028&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85089478577&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85089478577&origin=inward
- ID情報
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- DOI : 10.1039/d0ta05489e
- ISSN : 2050-7488
- eISSN : 2050-7496
- ORCIDのPut Code : 86494104
- SCOPUS ID : 85089478577
- Web of Science ID : WOS:000548452100028