Papers

Peer-reviewed
Aug, 2007

Rhenium-catalyzed synthesis of naphthalene derivatives via insertion of aldehydes into a C-H bond

TETRAHEDRON
  • Yoichiro Kuninobu
    • ,
  • Yuta Nishina
    • ,
  • Kazuhiko Takai
Volume
63
Number
35
First page
8463
Last page
8468
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1016/j.tet.2007.05.083
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Arhenium complex, [ReBr(CO)(3)(THF)](2), catalyzed reactions of aromatic ketimines and aldehydes with dienophiles, followed by dehydration, to give naphthalene derivatives in good to excellent yields. This reaction proceeds via C-H bond activation, insertion of an aldehyde, intramolecular nucleophilic cyclization, reductive elimination, elimination of aniline and Diels-Alder reaction. After dehydration, naphthalene derivatives were formed. (c) 2007 Elsevier Ltd. All rights reserved.
Link information
DOI
https://doi.org/10.1016/j.tet.2007.05.083
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000252091600011&DestApp=WOS_CPL
ID information
  • DOI : 10.1016/j.tet.2007.05.083
  • ISSN : 0040-4020
  • Web of Science ID : WOS:000252091600011
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