Papers

Peer-reviewed
Aug, 2011

Facile Sc(OTf)(3)-Catalyzed Generation and Successive Aromatization of Isobenzofuran from o-Dicarbonylbenzenes

ORGANIC LETTERS
  • Yuta Nishina
    • ,
  • Tatsuya Kida
    • ,
  • Tomonari Ureshino
Volume
13
Number
15
First page
3960
Last page
3963
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1021/ol201479p
Publisher
AMER CHEMICAL SOC
Isobenzofuran can be prepared from o-phthalaldehyde using hydrosilane. The formed isobenzofuran Is trapped by an alkene via a Diels-Alder reaction. Further dehydration proceeds to furnish the conjugated aromatic compound. This multistep reaction was promoted by catalytic amounts of Sc(OTf)(3).
Link information
DOI
https://doi.org/10.1021/ol201479p
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000293252800049&DestApp=WOS_CPL
ID information
  • DOI : 10.1021/ol201479p
  • ISSN : 1523-7060
  • eISSN : 1523-7052
  • Web of Science ID : WOS:000293252800049
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