2006年3月
Liquid phase sintering and mechanical properties of SiC with rare-earth oxide
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
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- 巻
- 114
- 号
- 1327
- 開始ページ
- 247
- 終了ページ
- 252
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- 出版者・発行元
- CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI
A SiC powder of median size 0.8 mu m was mixed with polyacrylic acid (PAA, dispersant) in a 0.3 mol/1-R (NO3) 3 solution (R = Yb, Y, Gd, Sm, Nd and La) at pH 5 to adsorb uniformly the sintering additive (R 31 ion) on the SiC surface. The aqueous 30 vol% SiC suspension with 0.52 mass% PAA and 1.50 mass% R2O3 (as R(NO3)3), relative to SiC, was consolidated by filtration through a gypsum mold to form green compacts of 50-52% of theoretical density. The consolidated green compacts were densified with grain growth to 76-99% relative density by hot-pressing under a pressure of 39 MPa at 1950 degrees C for 2 h in an Ar flow. The addition of R2O3 of smaller R3+ ion was effective to enhance the sinterability of SiC and also to achieve smaller grain size of SiC. This result was discussed based on the additional experiment result on the chemical interaction between SiC compact and the SiO2-R2O3 liquid. The average flexural strength and Weibull modulus of dense SiC were 612 Wa and 5.1, 719 Wa and 6.7, and 731 MPa and 9.8 for Gd2O3, Y2O3 and Yb2O3 addition, respectively.
- リンク情報
- ID情報
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- ISSN : 1882-0743
- eISSN : 1348-6535
- Web of Science ID : WOS:000236616600005