論文

査読有り 筆頭著者 責任著者
2016年6月21日

Self-diffusion of protons in H2O ice VII at high pressures: Anomaly around 10 GPa

The Journal of Chemical Physics
  • Naoki Noguchi
  • ,
  • T. Okuchi

Vol.144
No.23
開始ページ
234503-1
終了ページ
234503-9
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1063/1.4953688

The self-diffusion of ice VII in the pressure range of 5.5-17 GPa and temperature range of 400-425 K was studied using micro Raman spectroscopy and a diamond anvil cell. The diffusion was monitored by observing the distribution of isotope tracers: D2O and H2 (18)O. The diffusion coefficient of hydrogen reached a maximum value around 10 GPa. It was two orders of magnitude greater at 10 GPa than at 6 GPa. Hydrogen diffusion was much faster than oxygen diffusion, which indicates that protonic diffusion is the dominant mechanism for the diffusion of hydrogen in ice VII. This mechanism is in remarkable contrast to the self-diffusion in ice Ih that is dominated by an interstitial mechanism for the whole water molecule. An anomaly around 10 GPa in ice VII indicates that the rate-determining process for the proton diffusion changes from the diffusion of ionic defects to the diffusion of rotational defects, which was suggested by proton conductivity measurements and molecular dynamics simulations.

リンク情報
DOI
https://doi.org/10.1063/1.4953688
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/27334175
ID情報
  • DOI : 10.1063/1.4953688
  • ISSN : 1089-7690
  • PubMed ID : 27334175

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