Megasplay fault branching from plate boundaries of subduction zones is thought to be important sources of earthquakes and tsunamis. In this study, we performed structural and geochemical analyses on a fossilized megasplay fault (the Nobeoka Thrust of the Shimanto accretionary complex) to understand fluid-rock interaction and how the splay fault plays a role in fluid flow in the seismogenic zone. As a result of structural observations, we report that the principal slip zone (PSZ) of the Nobeoka Thrust is composed of foliated cataclasite originating from a sandstone-shale melange and includes a thin (similar to 1.5mm thick) pseudotachylyte layer. Major and trace element composition analysis and EPMA element mapping revealed that the pseudotachylyte is enriched in Li and Cs within the PSZ, as well as in the slip zone of a minor fault in the footwall. Li and Cs enrichment in pseudotachylyte is interpreted as a result of fluid-rock interaction in the postseismic stage, because such an anomaly only results from a large fluid/rock ratio (R >512-24 at 250-350 degrees C) under the influence of Li- and Cs-enriched fluids. The amount of fluid that reacted with the pseudotachylyte is estimated to be 1.78x10(0) to 7.61x10(3)m(3).