2012年
Hydrogenation effects in metalloporphycenes: synthesis and redox behavior of Ni(II)-tetra(n-propyl)dihydroporphycene
CHEMICAL COMMUNICATIONS
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- 巻
- 48
- 号
- 44
- 開始ページ
- 5413
- 終了ページ
- 5415
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c2cc30991b
- 出版者・発行元
- ROYAL SOC CHEMISTRY
Hydrogenated tetrapropylporphycenes, 2,3-dihydro-2,7,12,17-tetrapropylporphycene 1 and its Ni-II complex 2, have been prepared and the hydrogenation effects on their electronic structure characterized. A one-electron reduction of 2 promotes dehalogenation of organic halides whose observation is unprecedented for the porphycene compounds.
- リンク情報
- ID情報
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- DOI : 10.1039/c2cc30991b
- ISSN : 1359-7345
- eISSN : 1364-548X
- PubMed ID : 22510782
- Web of Science ID : WOS:000303774000003