2018年
Micro-organic ion-associate phase extraction/micro-volume back-extraction for the preconcentration and GF-AAS Determination of cadmium, nickel and lead in environmental water
Analytical Sciences
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- 巻
- 34
- 号
- 12
- 開始ページ
- 1445
- 終了ページ
- 1448
- DOI
- 10.2116/analsci.18N011
- 出版者・発行元
- Japan Society for Analytical Chemistry
© 2018 The Japan Society for Analytical Chemistry. Micro-organic ion-associate phase (IAP) extraction was combined with a micro-volume back-extraction (MVBE) to reduce coexisting components and viscosity in the concentrates. Heavy metals were converted into a complex with 2-(5-bromo- 2-pyridylazo)-5-(N-propyl-N-sulfopropylamino)phenol in a 40-mL sample solution, and were extracted into ion associates. After centrifugation and discarding the aqueous phase, trace metals were stripped from IAP into a nitric acid solution, followed by GF-AAS determination. Only one vessel was required for 400-fold enrichment. The detection limits (3σ b ) for Cd, Ni, and Pb were 0.6, 3.7, and 0.8 ng/L, respectively. This method was applied in recovery tests in seawater.
- リンク情報
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- DOI
- https://doi.org/10.2116/analsci.18N011
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/30197383
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85058057320&origin=inward 本文へのリンクあり
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85058057320&origin=inward
- URL
- http://orcid.org/0000-0002-1008-7037
- ID情報
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- DOI : 10.2116/analsci.18N011
- ISSN : 0910-6340
- eISSN : 1348-2246
- ORCIDのPut Code : 48360246
- PubMed ID : 30197383
- SCOPUS ID : 85058057320