論文

査読有り
2016年12月

Molybdenum-Catalyzed Stereospecific Deoxygenation of Epoxides to Alkenes

ADVANCED SYNTHESIS & CATALYSIS
  • Sobi Asako
  • ,
  • Takahisa Sakae
  • ,
  • Masahito Murai
  • ,
  • Kazuhiko Takai

358
24
開始ページ
3966
終了ページ
3970
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/adsc.201600840
出版者・発行元
WILEY-V C H VERLAG GMBH

Mild and simple catalytic systems consisting of molybdenum(VI) dichloride dioxide [MoO2Cl2] as a catalyst and a phosphine as reductant have been developed for the stereospecific deoxygenation of epoxides to alkenes. The reactions using 1,2-bis(diphenylphosphino)ethane (dppe) and triphenylphosphine (PPh3) proceed with retention and inversion of stereochemistry, respectively. The mild reaction tolerates the presence of various functional groups and affords stereodefined substituted olefins in good yields.

Web of Science ® 被引用回数 : 10

リンク情報
DOI
https://doi.org/10.1002/adsc.201600840
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000391810000008&DestApp=WOS_CPL
URL
http://orcid.org/0000-0003-4525-5317

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