論文

査読有り
2015年7月

Iron-Catalyzed Directed Alkylation of Alkenes and Arenes with Alkylzinc Halides

ADVANCED SYNTHESIS & CATALYSIS
  • Laurean Ilies
  • ,
  • Saki Ichikawa
  • ,
  • Sobi Asako
  • ,
  • Tatsuaki Matsubara
  • ,
  • Eiichi Nakamura

357
10
開始ページ
2175
終了ページ
2179
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/adsc.201500276
出版者・発行元
WILEY-V C H VERLAG GMBH

Alkenes and arenes possessing a bidentate directing group are alkylated with a primary or secondary alkylzinc halide in the presence of an iron/diphosphine catalyst and a dichloroalkane oxidant. Acrylamides, including unsubstituted and monosubstituted ones, react stereoselectively. Under these reaction conditions, beta-hydrogen elimination and homocoupling of the organometallic reagent are largely suppressed. The reaction may proceed through C-H activation catalyzed by an organoiron(III) species.

Web of Science ® 被引用回数 : 47

リンク情報
DOI
https://doi.org/10.1002/adsc.201500276
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000358208000002&DestApp=WOS_CPL
URL
http://orcid.org/0000-0003-4525-5317

エクスポート
BibTeX RIS