論文

査読有り
2014年10月

Iron-Catalyzed C(sp(2))-H Bond Functionalization with Organoboron Compounds

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Rui Shang
  • ,
  • Laurean Ilies
  • ,
  • Sobi Asako
  • ,
  • Eiichi Nakamura

136
41
開始ページ
14349
終了ページ
14352
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ja5070763
出版者・発行元
AMER CHEMICAL SOC

We report here that an iron-catalyzed directed CH functionalization reaction allows the coupling of a variety of aromatic, heteroaromatic, and olefinic substrates with alkenyl and aryl boron compounds under mild oxidative conditions. We rationalize these results by the involvement of an organoiron(III) reactive intermediate that is responsible for the CH bond-activation process. A zinc salt is crucial to promote the transfer of the organic group from the boron atom to the iron(III) atom.

Web of Science ® 被引用回数 : 110

リンク情報
DOI
https://doi.org/10.1021/ja5070763
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000343276900006&DestApp=WOS_CPL
URL
http://orcid.org/0000-0003-4525-5317

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