論文

査読有り
2014年9月

Iron-Catalyzed Directed Alkylation of Aromatic and Olefinic Carboxamides with Primary and Secondary Alkyl Tosylates, Mesylates, and Halides

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Laurean Ilies
  • ,
  • Tatsuaki Matsubara
  • ,
  • Saki Ichikawa
  • ,
  • Sobi Asako
  • ,
  • Eiichi Nakamura

136
38
開始ページ
13126
終了ページ
13129
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ja5066015
出版者・発行元
AMER CHEMICAL SOC

Alkenes, arenes, and heteroarenes possessing an 8-quinolylamide group as the directing group are alkylated with primary and secondary alkyl tosylates, mesylate, and halides in the presence of Fe(acac)(3)/diphosphine as a catalyst and ArZnBr as a base. The reaction proceeds stereospecifically for alkene substrates and takes place without loss of regiochemical integrity of the starting secondary tosylate, but with loss of the stereochemistry of the chiral center.

Web of Science ® 被引用回数 : 110

リンク情報
DOI
https://doi.org/10.1021/ja5066015
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000342328200014&DestApp=WOS_CPL
URL
http://orcid.org/0000-0003-4525-5317

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