論文

査読有り
2013年11月

Iron-Catalyzed Ortho-Allylation of Aromatic Carboxamides with Allyl Ethers

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Sobi Asako
  • ,
  • Laurean Ilies
  • ,
  • Eiichi Nakamura

135
47
開始ページ
17755
終了ページ
17757
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ja4106368
出版者・発行元
AMER CHEMICAL SOC

Arenes possessing an N-(quinolin-8-yl)-amide directing group are ortho-allylated with allyl phenyl ether in the presence of an iron/diphosphine catalyst and an organometallic base at 50-70 degrees C. The reaction proceeds via fast iron-catalyzed C-H activation, followed by reaction of the resulting iron intermediate with the allyl ether in gamma-selective fashion.

Web of Science ® 被引用回数 : 161

リンク情報
DOI
https://doi.org/10.1021/ja4106368
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000328099400026&DestApp=WOS_CPL
URL
http://orcid.org/0000-0003-4525-5317

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