MISC

2005年10月

Synthesis of bis(phenoxyimine) Ti alkyl complexes and observation of living species by H-1 NMR spectroscopy

CHEMISTRY LETTERS
  • H Makio
  • ,
  • T Oshiki
  • ,
  • K Takai
  • ,
  • T Fujita

34
10
開始ページ
1382
終了ページ
1383
記述言語
英語
掲載種別
DOI
10.1246/cl.2005.1382
出版者・発行元
CHEMICAL SOC JAPAN

Synthesis of [C6F5N=CH(2-O-C6H3-3-R)](2)TiMex (R: Bu-t; X: Br (2), R: Bu-t; X: Me (3), R: H; X: Me (4)) was achieved by the reaction of methylated titanium halides with sodium salts of the phenoxyimine ligands. These complexes can be activated with equimolar amounts of B(C6F5)(3) or Ph3CB(C6F5)(4) to form methyl cationic species, which, upon addition of a small amount of ethylene monomer allows room temperature observation of cationic polymeryl species.

リンク情報
DOI
https://doi.org/10.1246/cl.2005.1382
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000232745400038&DestApp=WOS_CPL
ID情報
  • DOI : 10.1246/cl.2005.1382
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • Web of Science ID : WOS:000232745400038

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