2005年10月
A novel heteroligated phenoxy-based titanium complex: Structure, stability, and ethylene polymerization behavior
CHEMISTRY LETTERS
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- 巻
- 34
- 号
- 10
- 開始ページ
- 1458
- 終了ページ
- 1459
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.2005.1458
- 出版者・発行元
- CHEMICAL SOC JAPAN
A new phenoxy-imine and phenoxy-ketone heteroligated titanium complex was obtained by hydrolysis of one of the two imine moieties of a bis(phenoxy-imine)Ti complex. X-ray diffraction analysis revealed that the complex assumes an octahedral coordination geometry with a cis-phenoxy-O's and cis-Cl's disposition. NMR studies demonstrated that the complex does not undergo disproportionation. In association with methylaluminoxane, the complex behaved as a non-living-type single-site catalyst for ethylene polymerization.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.2005.1458
- ISSN : 0366-7022
- eISSN : 1348-0715
- CiNii Articles ID : 10019352667
- Web of Science ID : WOS:000232745400076