論文

2005年10月

A novel heteroligated phenoxy-based titanium complex: Structure, stability, and ethylene polymerization behavior

CHEMISTRY LETTERS
  • Y Suzuki
  • ,
  • T Oshiki
  • ,
  • H Tanaka
  • ,
  • K Takai
  • ,
  • T Fujita

34
10
開始ページ
1458
終了ページ
1459
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/cl.2005.1458
出版者・発行元
CHEMICAL SOC JAPAN

A new phenoxy-imine and phenoxy-ketone heteroligated titanium complex was obtained by hydrolysis of one of the two imine moieties of a bis(phenoxy-imine)Ti complex. X-ray diffraction analysis revealed that the complex assumes an octahedral coordination geometry with a cis-phenoxy-O's and cis-Cl's disposition. NMR studies demonstrated that the complex does not undergo disproportionation. In association with methylaluminoxane, the complex behaved as a non-living-type single-site catalyst for ethylene polymerization.

リンク情報
DOI
https://doi.org/10.1246/cl.2005.1458
CiNii Articles
http://ci.nii.ac.jp/naid/10019352667
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000232745400076&DestApp=WOS_CPL
ID情報
  • DOI : 10.1246/cl.2005.1458
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • CiNii Articles ID : 10019352667
  • Web of Science ID : WOS:000232745400076

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