2003年10月14日
PB16 酸化還元活性金属錯体を用いた新規錯体液晶群の創成(化学・材料)
日本液晶学会討論会講演予稿集
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- 巻
- 2003
- 号
- 2003
- 開始ページ
- 389
- 終了ページ
- 390
- 記述言語
- 日本語
- 掲載種別
- DOI
- 10.11538/ekitou.2003.0_389
- 出版者・発行元
- 日本液晶学会
Novel mono/trinuclear palladium/platinum complexes have been synthesized and characterized by X-ray diffraction, electrochemical, and thermogravimetric analyses. All the complexes possess catecholate derivatives, which have been known to show rich redox activity. Almost complexes show multi-step thermal phase transitions, and each transition was studied by XRPD and DSC measurements. Interestingly, the complexes demonstrate redox activity based on the electronically labile nature of the catecholate derivatives. The results obtained in this study clearly suggest that the complexes would be candidates for redox-active metallomesogens.
- リンク情報
- ID情報
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- DOI : 10.11538/ekitou.2003.0_389
- CiNii Articles ID : 110001482356
- CiNii Books ID : AA11639022
- identifiers.cinii_nr_id : 1000020140303