The transition metal coordination polymers are of substantial interest in providing unprecedented novel solid properties based on co-operation of electronic, optical and magnetic phenomena. However, there have beeen no such compounds that localized spins and delocalized conducting electrons are coupled on the 2-dimensional layers. This is due to the lack of rational synthesis to link polymer motifs of metal complexes. This is synthetic research to create various type of 1-and 2-dimensional copper coordination compounds.