2014年
Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series
CHEMICAL COMMUNICATIONS
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- 巻
- 50
- 号
- 24
- 開始ページ
- 3238
- 終了ページ
- 3241
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c4cc00700j
- 出版者・発行元
- ROYAL SOC CHEMISTRY
The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption.
- リンク情報
- ID情報
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- DOI : 10.1039/c4cc00700j
- ISSN : 1359-7345
- eISSN : 1364-548X
- Web of Science ID : WOS:000332115400030