2015年2月
Study on a 2D layer coordination framework showing order-to-disorder phase transition by ionothermal synthesis
POLYMER JOURNAL
- ,
- ,
- ,
- 巻
- 47
- 号
- 2
- 開始ページ
- 141
- 終了ページ
- 145
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1038/pj.2014.100
- 出版者・発行元
- NATURE PUBLISHING GROUP
In this study, a two-dimensional (2D) layer-type coordination framework showing solid-to-solid phase transition was ionothermally synthesized. [Zn-2(SO4)(3)(bpy)](THMA)(2) contains an anionic 2D grid layer-type coordination framework and an ordered bulky ammonium cation, THMA(+), with multiple hydrogen bonds. The compound shows reversible order-to-disorder transformation, a result of the cations, which were characterized using X-ray diffraction, differential scanning calorimetry and solid state nuclear magnetic resonance. This study suggests the potential use of coordination frameworks, prepared by ionothermal synthesis, in the design of new type of materials that show solid-to-solid phase transition and high thermal stability for dielectric, ferroelectric and electro-optic functions.
- リンク情報
- ID情報
-
- DOI : 10.1038/pj.2014.100
- ISSN : 0032-3896
- eISSN : 1349-0540
- Web of Science ID : WOS:000349473600011