2014年11月
Controlled Cyclopolymerization of Difunctional Vinyl Monomers in Coordination Nanochannels
MACROMOLECULES
- ,
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- 巻
- 47
- 号
- 21
- 開始ページ
- 7321
- 終了ページ
- 7326
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ma501232n
- 出版者・発行元
- AMER CHEMICAL SOC
Radical cyclopolymerization of difunctional monomers based on 1,6-diene components was performed in one-dimensional channels of porous coordination polymers (PCPs). Although bulk or solution polymerization of the monomers usually gives cross-linked insoluble polymers, the unfavorable interpolymer reactions were effectively suppressed in the narrow nanochannels of PCPs to provide soluble linear polymers. The pore matrices and functionality of PCPs can be readily designed by changing the organic ligands, so that polymerization of the diene monomers in different sized pores was examined. The primary structures of the resulting polymers, such as branching, cyclic structure, and stereoregularity, were changed, depending on the pore characteristics of the PCPs.
- リンク情報
- ID情報
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- DOI : 10.1021/ma501232n
- ISSN : 0024-9297
- eISSN : 1520-5835
- Web of Science ID : WOS:000344905800007