2014年
Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction
CHEMICAL COMMUNICATIONS
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- 巻
- 50
- 号
- 71
- 開始ページ
- 10241
- 終了ページ
- 10243
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c4cc04370g
- 出版者・発行元
- ROYAL SOC CHEMISTRY
We observed an ordered-to-disordered structural transformation in a Cu2+ coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10(-2) S cm(-1) at 130 degrees C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR.
- リンク情報
- ID情報
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- DOI : 10.1039/c4cc04370g
- ISSN : 1359-7345
- eISSN : 1364-548X
- Web of Science ID : WOS:000340896900014